The first-gen S-Type R had the same brakes as the S-Type, essentially. It was just a bigger engine, with some mild suspension tuning.
The second-gen S-Type R introduced a Super-Charger, Brembo big-brakes, lowered ride height, higher and dual rate springs, re-tuned suspension, different sway bars, some upgraded suspension parts, and re-tuned computer tunes.
The third gen was a downgrade. The S-type went to a single-piston brake caliper, and was mostly a supercharged s-type with different electronic tuning. I think they retained different swaybars and tire/rim packages.
The XFR follows the same format as the third-gen S-Type R, which is mostly just a big engine and sway bars. They rely on the electronic tuning to handle the rest. They did upgrade the XF to have the same size front and rear rotors for the stability control system.